NAVAL APPLICATIONS,
ATTACK SUBMARINES
AIP – Fuel Cell or IHD – AIP
INDEX
INTRODUCTION
Potential Fuel Cell Power Plants & The IHD-AIP Alternative
(Stirling Cycle Power Plants Not Addressed Due To Limitations In Power Density)AIP-
FUEL CELL SUBMARINES,
Phosphoric Acid Fuel Cells (PAFC)
Molten Carbonate Fuel Cells (MCFC)
General Observation
IHD-AIP SUBMARINES – THE ALTERNATIVE.
Integrated Hydraulic Diesel - Air Independent Power (IHD-AIP) Plant
1. INTRODUCTION
Potential Fuel Cell Power Plants & The IHD-AIP Alternative
(Stirling Cycle Power Plants Not Addressed Due To Limitations In Power Density)
Through-out this address, IHD-AIP is considered to be an address of an “Integrated Hydraulic Diesel - Air Independent Power Plant” operating in a Re-Cycle Diesel Mode and the following is an operational comparison with what are currently considered, potentially, the two most powerful forms of Fuel Cell.
Although there are great expectations for fuel cell power plants in AIP submarines, as typified by the Russian-made submarines equipped with the Kristall electrochemical generator (fuel cell) AIP plant; as yet there is little real progress towards the availability of such fuel cells in the MW (continuous) range, suitable for use as AIP plant in submarines. There is little to promote the expectation this circumstance will change in the near future.
Irrespective of there currently being in operation a number of existing civil fuel cell generator systems, with an acknowledged operational capacity in the MW range, these have for the most part been basically experimental power plants, with the greater portion of these systems being Phosphoric Acid Fuel Cells (PAFC). In parallel with this, development of Molten Carbonate Fuel Cells (MCFC) likewise holds promise, although as things currently stand, neither of these types is yet well suited to use as a submarine power plant.
2. AIP-FUEL CELL SUBMARINES
Phosphoric Acid Fuel Cells (PAFC)
In the case of PAFCs, the American DoD has for some time now, been operating a number of sub-MW land units as supplemental power plants on various military bases, principally to gain operational data on the type. These units appear to be almost exclusively PAFC type systems and of modest power capabilities. As long ago as the early eighties, PAFC systems were built in the United States with 7.5 MW and 11 MW capacities. With the former subsequently sold to interests in Japan, where it and a lesser 4.8 MW unit of Japanese manufacture, were still in operation, well into the mid-nineties. Not with standing these long-term demonstrations of the viability of PAFC units, in ostensibly civil applications and the demonstrated tolerance of impurities in both fuels and oxidants. Although the PAFC type has a notable operational history, as above, they are never the less, not well suited to submarine applications for a number of technical reasons, including:
· a corrosive electrolyte operating at elevated temperatures with a requirement for demanding storage facilities,
· solidification of the electrolyte at room temperature, in combination with a hygroscopic disposition,
protracted and slow warm through requirements on start-up and demanding cool-down procedures on shut-down,
· the combination of a high operating temperature and corrosive electrolyte results in the use of materials that are brittle and susceptible to shock damage,
· the elevated operational temperatures required for good power densities, is conducive to the phosphoric acid corroding carbon catalyst support and similarly damaging graphic bi-polar plates, whist the catalyst also suffers degradation during operation
There are also a number of individually minor, shipboard environmental liabilities that likewise reduce the viability of PAFC to use as AIP submarine power plants. These include contamination of product water and minor vapor diffusion to the atmosphere. Although power densities of PAFC, in general, is unremarkable, the more compact versions of the type would be acceptable as AIP units, were it not for the sum of the minor disadvantages associated with the type.
Molten Carbonate Fuel Cells (MCFC)
MCFCs have been demonstrated to at least 1.8 MW and with their very high operational temperatures, provide an ability to use internal reforming, when operating on directly introduced vaporous methanol fuel; resulting in reductions in heat, fuel and oxidant losses along with the electrical consumption usually associated with an external reformer, purification, discharge and recycle systems. Total system electrical generation efficiency is, as a consequence, potentially very close to the actual fuel cell efficiency and arguably higher than an equivalent Proton Exchange Membrane Fuel Cell (PEMFC) system. The problems associated with warm-through and cool down cycles are consistent with PAFCs, with the proviso that delinquent temperature control will not adversely effect the platinum catalyst’s performance.
Unfortunately, the use of methanol as a fuel invokes a number of significant penalties. When considering vessels with equivalent MCFC-AIP operational ranges, the first using diesel fuel and the second methanol, the diesel-fuelled vessel has a requirement for approximately 60%, by weight, of the fuel and oxidant of the methanol powered vessel. Given the current projections for MCFC systems, it is unlikely such power plants will result in a single power plant type vessel and as such, a diesel power plant is likely to continue as a major element of this type. If a dual fuel system and the resulting complexity is not to be the result, this will likewise dictate the use of diesel fuelled MCFC.
However, when operating on diesel fuel, the ability to rely on internal reforming must be forgone, in order to prevent soot formation and subsequent contamination problems. In such circumstances, an external reformer is a requirement, further resulting in a requirement to then use sulphur free diesel fuel. However, with the acceptability of carbon monoxide as a fuel component, there is no requirement for a low temperature shift stage to overcome what would otherwise constitute a contaminant in lower temperature fuel cell systems, running on hydrogen reformed from diesel fuel. Although MCFCs have a reduced level of requirement for external reformers, the requirement for sulphur free diesel when operating on diesel fuel as the consumable, represents quite a notable limitation, with regards the integration of an AIP submarine powered by a MCFC into an existing fleet, as it constitutes a requirement for an additional fuel type. This will, of necessity, result in a duplicate and dedicated shore-side storage and bunkering systems, to eliminate the potential for accidental cross-contamination with sulphurous fuels used in alternative applications.
The sum of the above, tends to preclude the advantages of relative simplicity, associated with civil MCFC systems, being gained in the use of MCFC as an AIP submarine power plant.
General Observation
The remarks regarding the protracted and slow warm through requirements on start-up of the above high temperature fuel cells, should be considered with a degree of caution; this is probably no more problematical than is charging-up batteries from cold and it is worth considering that such high temperature fuel cells are, once hot, highly responsive to load variations.
(Continued - Nero)